La/ d o n / ^ / J ^ 2 1 Enhancement of Mechanical Properties in the Heat Affected Zone of A A 5083 Weld Joints W. U. S. Mirihanage "'''-v.'z-y T h i s T h e s i s w a s s u b m i t t e d to t h e D e p a r t m e n t o f M a t e r i a l s E n g i n e e r i n g o f t h e U n i v e r s i t y o f M o r a t u w a i n p a r t i a l f u l f i l l m e n t o f the r e q u i r e m e n t s f o r t h e D e g r e e o f M a s t e r o f P h i l o s o p h y . 8 3 8 1 1 University of Moratuwa //tS^^ D e p a r t m e n t o f M a t e r i a l s E n g i n e e r i n g G ^ y U n i v e r s i t y o f M o r a t u w a , S r i L a n k a . 1 5 - 0 5 - 2 0 0 5 0 3 6 1 / 83811 D E C L A R A T I O N I certify that the Thesis with the title " Enhancement of Mechanical Properties in the Heat Affected Zone of A A 5083 Weld Joints " is entirely my own work. It has not been accepted for any degree and it is not being submitted for any other degree. Candidate W. U. S. Mirihanage Signature Date Supervisor Dr. N . Munasinghe Signature A C K N O W L E D G M E N T Initially, I would like to thank my supervisor Dr. Nanda Munasinghe for his guidance, support and encouragement. Then, to Dr. Rohan Thitagala for his kind and supportive advices, Commander Lalith Alahakone and Lieutenant Senaka Kumarasinghe of Sri Lanka Navy for their support and co-operation had given to my studies about the weld defects in marine applications. In addition to that, 1 like to express my gratitude to Dr. S. U. Adikary and all the academic and non-academic staff of the Department of Materials Engineering, University of Moratuwa for their help and contribution for my research. Same time I appreciate and thank to Prof. Jayasinghe of Engineering Design Center, CAD/CAM/CAE and workshop staff of Department of Mechanical Engineering at University of Moratuwa, Department of Botany, University of Colombo and Colombo Dockyard Ltd. staff for their support and assistance. I must be indebted to Asian Development Bank funded personal development project for their awarding of a full scholarship for entire studies. At last but not least, it is indeed to thank my mother, father and my wife Nadeesha for their encouragement, support and sacrifice. Wajira U. S. Mirihanage Department of Materials Engineering, University of Moratuawa. 15 t h March 2005 Acknowledgement in ABSTRACT Decline of Mechanical properties were observed at the Heat Affected Zone (HAZ) of the Gas Metallic Arc Weld (GMAW) joints of the Aluminium Alloy (AA) 5083. It was concerned as a direct effect of the weld thermal cycle on the work hardened material. Experimental efforts were aimed to set up a post welding procedure to recover this decline of properties. Presence of the Silicon in AA 5083 was significant in the experimental considerations due to its tendency of forming M g 2 S i precipitates at intensified temperatures. A series of mechanical and microstructure observations were done to evaluate the effectiveness of the post weld heat treatment, with the AA 5083. According to the experimental results heat treatment at 473K for 10 minutes produced the most effective improvement of mechanical properties at the HAZ of weld joint. Abstract ii CONTENT Declaration i Abstract ii Acknowledgement iii Content iv List of Figures vi 1. Introduction 01 2. Literature Review 02 2.1 Aluminum - Introduction to the Material 02 2.2 Aluminum - History and Extraction Process 03 2.3 Classification of Aluminum and Aluminum alloys 05 2.4 Engineering Applications of Aluminum and Aluminum alloys II 2.5 Concerning Factors in Application of Aluminum Alloys 16 2.6 Characteristics of AA 5083 and other 5xxx series alloys 20 2.7 Welding of Aluminum alloys 24 2.6 Gas Metallic Arc Welding(GMAW) Process 28 3. Problem Analysis 33 3.1 Defect analysis of AA 5083 GMAW joints 33 3.2 Material Characteristics of AA 5083 welded joints 38 4. Experimental Results 39 4.1 Materials Testing Equipments 39 4.2 Chemical composition & Mechanical properties of AA 5083 43 4.3 Variation of mechanical Properties along the AA 5083 G M A W joint 45 Content 4.4 Affects of heat on hardness of AA 5083 48 4.5 Variation in Mechanical Properties of Heat Treated AA 5083 GMAW Joints 49 4.6 Microstructure of AA 5083 (as received condition) 61 4.7 Microstructure variation along the AA 5083 GMAW joint 63 4.8 Affects of Heat on AA 5083 microstructure 65 4.9 Microstructure variations on heat treated AA 5083 GMAWjoin t s 66 4.10 Experimental Limitations and further work 67 5. Discussion 68 5.1 Weld Thermal Cycle 68 5.2 Improvement Properties HAZ by Heat Treatment 69 5.3 Metallurgical Approach to Behavior of Precipitates 70 5.4 Practical Utilization of Experimental Results and further work 75 6. Conclusion 76 7. References 77 8. Annexes 80 Content LIST OF FIGURES AND TABLES Figures Fig. No. 2.1 FCC structure of Aluminum unit cell 02 Fig. No. 2.2 Aluminum extraction process 05 Fig. No. 2.3 Gas Metallic Arc Welding Diagram 29 Fig. No. 3.1 Insufficient weld penetration 33 Fig. No. 3.2 Undercut 34 Fig. No. 3.3 Reinforcement too high 34 Fig. No. 3.4 Too much root penetration 34 Fig. No. 3.5 Edge misalignment 35 Fig. No. 3.6 Porosity at aluminum weld joint 35 Fig. No. 3.7.(a)Single pores 36 Fig. No. 3.7.(b)Pore clusters 36 Fig. No. 3.7.(c)Liner porosity 36 Fig. No. 4.1 GMAW welding plant 39 Fig. No. 4.2 Hounsfield Tensometer 39 Fig. No. 4.3 Microhardness Tester 40 Fig. No. 4.4 Vickers Hardness Tester 40 Fig. No. 4.5 (a)Grinding equipment 41 Fig. No. 4.5 (b) Polishers 41 Fig. No. 4.6 Metallurgical Microscope 42 Fig. No. 4.7 Scanning Electron Microscope 42 Fig. No. 4.8 Atomic Absorption Spectrometer 42 Fig. No. 4.9 AA 5083 Stress - Strain curve of AA 5083 45 Fig. No. 4.10 Variation of hardness along the AA 5083 GMAW joint 46 Fig. No. 4.11 Tensile samples to test weld joint properties 47 Fig. No. 4.12 Stress-Strain diagrams for Zones of AA 5083 weld joint 47 List of Figures and Tables Fig. No. 4.13 Hardness variation of Treated AA 5083 samples 49 Fig. No. 4.14 Hardness testing profile of weld joint 51 Fig. No. 4.15 Change of micro hardness of the cross section of the weld treated for 5 minutes at Different Temperatures 51 # Fig. No. 4.16 Change of micro hardness of the cross section of the weld treated for 10 minutes at different Temperatures 52 Fig. No. 4.17 Change of micro hardness of the cross section of the weld treated for 15 minutes at different Temperatures 52 Fig. No. 4.18 Change of micro hardness of the cross section of the weld treated for at 473 K for different time intervals 53 Fig. No. 4.19 Change of micro hardness of the cross section of the weld treated for at 473 K for different time intervals 53 Fig. No. 4.20 Tensile test sample preparation for Weld metal 55 Fig. No. 4.21 Stress-Strain curve for treated samples 56 Fig. No. 4.22 Tensile samples obtain from the HAZ of heat treated 57 > specimens Fig. No. 4.23 Change of Tensile Properties of the Heat Affected Zone treated for 5 Minutes 58 Fig. No. 4.24 Change of Tensile Properties of the Weld Metal Zone treated for 10 Minutes 59 Fig. No. 4.25 Change of Tensile Properties of the Heat Affected Zone treated for 15 Minutes 59 Fig. No. 4.26 Change of tensile properties of the Heat Affected Zone soaked at 473 K 60 Fig. No. 4.27 Change of tensile properties of the Heat Affected Zone treated at 673 K 60 Fig. No. 4.28 Micro Structure of AA 5083 etched after different etchants 62 Fig. No. 4.29 Microstructure Examination Points in weld joint 63 Fig. No. 4.30 Macro Photograph of AA 5083 Weld joint Cross Section 63 Fig. No. 4.31 Microstructure Photographs of Various Points of AA 5083 Weld Joint 64 Fig. No. 4.32 AA 5083 Heat Treated for Different Soaking Temperatures 65 Fig. No. 4.33 Microstructure - HAZ of AA 5083 Heat Treated at 473K 66 Fig. No. 4.34 Microstructure - HAZ of AA 5083 Heat Treated at 673K 66 List of Figures and Tables • Fig. No. 5.1 Temperature distribution during welding Fig. No. 5.2 Linear Relationship of Radius of the Precipitate and Soaking time Fig. No. 5.3 Movement of dislocations through precipitates Fig. No. 5.4 Average micro hardness vs. treated time 68 72 73 74 Tables Table 4.1 .a) Chemical composition of AA 5083 - Experimental values 43 Table4.1.b) Chemical composition of AA 5083 - Values by standards 43 Table 4.2 Comparison of Vickers and Microhardness Hardness 44 values of AA 5083 Table 4.3 Average hardness after heat treatment of AA 5083 base metal 48 Table 4.4 Heat treatment parameters for hardness testing 50 Table 4.5 Heat treatment parameters for tensile testing 57 Table 4.6 Chemical Attacks on Intermetallic Phases in AA 5083 61 List of Figures and Tables viii